Fevereiro 2015 vol. 1 num. 2 - XX Congresso Brasileiro de Engenharia Química

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MECHANICAL AND MICROSTRUCTURAL PROPERTIES OF PLLA / TPS / GELATIN EXTRUDED SHEETS

PIZZOLI, A. P. DE O. ; YAMASHITA, F. ; SHIRAI, M. A. ; LEIMANN, F. V. ;

Artigo:

Poly (L-lactic acid) (PLLA) and thermoplastic starch (TPS) have been largely applied in the biodegradable packaging development in order to reduce residues generated from traditional packaging. Besides these biopolymers gelatin is also an interesting biomaterial for the production of films by extrusion. In this work, blends of PLLA, TPS (glycerol as plasticizer) and different concentrations of gelatin (0, 3 and 5wt% in relation to TPS) were produced in a double twin-screw co-rotating extruder coupled to a roll laminator. Films mechanical properties were determined in texture analyzer and their microstructure by Scanning Electron Microscopy. The formulations without and with 5wt% of gelatin showed smoother surfaces. The intermediate formulations showed porous surface with non-plasticized starch granules. The fracture of all produced films showed voids in the structure. In general, the addition of gelatin at the films leaded to a hardness and tensile strength reduction.

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DOI: 10.5151/chemeng-cobeq2014-1701-17975-153026

Referências bibliográficas
  • [1] AHMAD, M.; BENJAKUL, S.; PRODPRAN, T.; AGUSTIN, T.W. Physico-mechanical and antimicrobial properties of gelatin film from the skin of unicorn leatherjacket incorporated with essential oils. Food Hydrocolloidi., v. 28, p.189-199, 2012.
  • [2] AL-HASSAN, A. A.; NORZIAH, M. Starch–gelatin edible films: Water vapor permeability and mechanical properties as affected by plasticizers. Food Hydrocolloid., v. 26, p. 108–117, 201
  • [3] ARVANITOYANNIS, I.; NAKAYAMA, A., AIBA, S. Edible films made from hydroxypropyl starch and gelatin and plasticized by polyols and water. Carbohyd Polym., v. 36, p. 105–119, 1998.
  • [4] BAI, H.; XU, J.; LIAO, P.; LIU, X. Mechanical and water Barrier properties of soy protein isolate film Incorporated with gelatin. J. Plast. Film Sheet., v. 29, n. 2, p. 174-188, 2013.
  • [5] BONILLA, J.; ATARÉS, L.; VARGAS, M.; CHIRALT, A. Properties of wheat starch film-forming dispersions and films as affected by chitosan addition. J Food Eng, v. 114, p. 303–312, 2013.
  • [6] BRANDELERO, R. P. H.; GROSSMANN,M.V.E .; YAMASHITA, F. Effect of the method of production of the blends on mechanical and tructural properties of biodegradable starch films produced by blown extrusion. Carbohyd Polym., v. 86, p. 1344-1350, 2011.
  • [7] CHIOU, B. S.; FRI, H. J.; BUSTILLOS, R. A.; GREGORSKI, K.S.; BECHTEL, P.J.; IMAM, S.H.; GLENN, G.M.; ORTS, W.J. Properties of electrospun pollock gelatin/poly(vinyl alcohol) and pollock gelatin/poly(lactic acid) fibers . Int J Biol Macromol., v. 5, p. 214-220, 2013.
  • [8] CONN , R. E.; KOLSTAD, J. J.; BORZELLECA , J. F.; DIXLER , D. S.; FILER, L. J.; La Du, Jr. B. N.; PARIZA , M. W. Safety Assessment of Polylactide (PLA) for Use as a Food-contact Polymer. Fd. Chem. Toxic., v. 33, p. 273-283, 1995.
  • [9] FAKHOURI, F. M.; DARYNE, C.; YAMASHITA, F.; MARTELLI, S. M.; JESUS, R. C.; ALGANER, K.; QUEIROZ, F. P. C.; MEI, L. H. I. Comparative study of Processing methods for starch/gelatin films. Carbohy. Polym., v. 95, p. 681-689, 2013.
  • [10] FAKHOURY, F. M.; MARTELLI, S. M.; BERTAN, L. C.; YAMASHITA, F.; MEI, L. H. I.; QUEIROZ, F. P. C. Edible films made from blends of manioc starch and gelatin: Influence of different types of plasticizer and different levels of macromolecules on their properties. Food Sci. Technol. Int., v. 49, p. 149-154, 2012.
  • [11] Área temática: Engenharia de Materiais e Nanotecnologia 7GUZMAN-SIELICKA, A.; JANIK, H.; SIELICKI, P. Proposal of New Starch-Blends Composition Quickly Degradable in Marine Environment. J. Polym. Environ., v. 21, p. 802–806, 2013.
  • [12] HEYDARI, A.; ALEMZADEH, I.; VOSSOUGHI, M. Functional properties of biodegradable corn starch nanocomposites for food packaging applications. Mater. Design.,v. 50, p. 954-961, 2013.
  • [13] KUCHAIYAPHUM, P.; PUNYODOM, W.; WATANESK, S.; RUANGSRI W. R. Composition Optimization of Polyvinyl Alcohol/Rice Starch/Silk Fibroin-Blended Films for Improving Its Eco-Friendly Packaging Properties. Appl. Polym.sci,. v. 129, n. 5, 20
  • [14] LIU, Y. S.; HUANG, Q. L.; KIECZLE, E. A.; MULLER, W. E. G.; FENG, Q. L. In vitro degradation of porous PLLA/pearl powder composite scaffolds. Mater Sci Eng., v. 38, p. 227-234, 20
  • [15] MAHALIK, N. P.; NAMBIAR, A. N. Trends in food packaging and manufacturing systems and technology. Trends Food Sci Tech., v. 21, p. 117-128, 2010.
  • [16] PERESSINI, D.; BRAVIN, B.; LAPASIN, R.; RIZZOTTI, C.; SENSIDONI, A. Starch–methylcellulose based edible films: rheological properties of film-forming dispersions. J. Food Eng., v. 59, p. 2-32, 2003.
  • [17] SHIRAI, M. A.; GROSSMANN, M. V. E.; YAMASHITA, F.; GARCIA, P. S.; MÜLLER, C. M. O. Development of biodegradable flexible films of starch and poly ( lactic acid ) plasticized with adipate or citrate esters. Carbohyd. Polym., v. 92, n. 1, p. 19–22, 2013.
  • [18] SIRACUSA, V.; BLANCO, I.; ROMANI, S.; TYLEWICZ, U.; ROCCULI, P.; Poly(lactic acid)-Modified Films for Food Packaging Application: Physical, Mechanical, and Barrier Behavior. J Appl Polym Sci., v. 125, p. 390–401, 2012.
  • [19] TAGHIZADEH, A.; SARAZIN, P.; FAVIS, B. D. High molecular weight plasticizers in thermoplastic starch/ polyethylene blends. J Mater Sci ., v. 48, p. 1799–1811, 2013.
  • [20] YANG, X.; XU, Q.; YAN, N.; SUI, G.; CAI, Q.; DENG, X. Structure and wettability relationship of coelectrospun poly (L-lactic acid)/gelatin composite fibrous mats. Polym. Adv. Technol., v. 22, p. 2222–2230, 2010.
  • [21] ZHANG, N.; LIU, H.; YUA, L.; LI, X.; ZHANG, L.; CHEN, L.; SHANKS, R. Developing gelatin–starch blends for use as capsule materials. Carbohyd Polym., v.92, p. 455–461, 2013.
  • [22] ZHAO, X.; LIU, W.; YAO, K. Preparation and Characterization of Biocompatible Poly(L -lactic acid)/Gelatin Blend Membrane. J. Appl. Polym. Sci., v. 101, p. 269–276, 2006.
Como citar:

PIZZOLI, A. P. DE O.; YAMASHITA, F.; SHIRAI, M. A.; LEIMANN, F. V.; "MECHANICAL AND MICROSTRUCTURAL PROPERTIES OF PLLA / TPS / GELATIN EXTRUDED SHEETS", p. 14164-14171 . In: Anais do XX Congresso Brasileiro de Engenharia Química - COBEQ 2014 [= Blucher Chemical Engineering Proceedings, v.1, n.2]. São Paulo: Blucher, 2015.
ISSN 2359-1757, DOI 10.5151/chemeng-cobeq2014-1701-17975-153026

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