Use of fractional factorial design for optimizing removal of nickel, copper, cadmium and lead by buriti modified fibers

Use of fractional factorial design for optimizing removal of nickel, copper, cadmium and lead by buriti modified fibers

MELO, D. Q.; OLIVEIRA1, J. T.; TEIXEIRA, R. N. P.; NASCIMENTO, R. F.; RAULINO, G. S. C.; VIDAL, C. B.

Artigo:

The adsorption of copper, cadmium, lead and nickel in mono-element and multi-element aqueous solutions onto buriti modified fibers was studied. The fractional factorial design 24-1 showed that pH, adsorbent mass, agitation rate and initial metal concentration influenced each metal adsorption differently. The kinetics and thermodynamic equilibrium parameters were obtained for all elements. The results showed that the order of mono-element adsorption for these three contaminants is NiAndgt; CdAndgt; PbAndgt; Cu. The adsorption kinetics were fitted to the pseudo-second order model, giving linear correlation coefficients higher than 0.98. The Langmuir isotherm provided the best fit with the monoelement experimental data. In this study, the multi-element system isotherms were also obtained and a significant difference was found in the competitiveness for the site and the adsorption capacity order was

The adsorption of copper, cadmium, lead and nickel in mono-element and multi-element aqueous solutions onto buriti modified fibers was studied. The fractional factorial design 24-1 showed that pH, adsorbent mass, agitation rate and initial metal concentration influenced each metal adsorption differently. The kinetics and thermodynamic equilibrium parameters were obtained for all elements. The results showed that the order of mono-element adsorption for these three contaminants is NiAndgt; CdAndgt; PbAndgt; Cu. The adsorption kinetics were fitted to the pseudo-second order model, giving linear correlation coefficients higher than 0.98. The Langmuir isotherm provided the best fit with the monoelement experimental data. In this study, the multi-element system isotherms were also obtained and a significant difference was found in the competitiveness for the site and the adsorption capacity order was

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DOI: 10.5151/chemeng-cobeq2014-1232-20357-170225

Referências bibliográficas

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• [3] MOREIRA, S. A.; SOUSA, F. W.; OLIVEIRA, A. G.; BRITO, E. S.; NASCIMENTO, R. F. Remoção de metais de solução aquosa usando bagaço de caju Quim. Nova. 2009, 32, 1717-1722.
• [4] NETO,V. O. S.; CARVALHO, T. V.; HONORATO, S. B.; GOMES, C. L.; FREITAS, F. C.; SILVA, M. A. A.; FREIRE, P. T. C.; NASCIMENTO, R. F. Coconut bagasse treated by thioureia/ammonia solution for cadmium removal: kinetics and adsorption equilibrium. Bioresources 2012, 7, 1504-1524.
• [5] SOUSA, F. W.; SILVA, M. J. B.; OLIVEIRA, I. R. N.; OLIVEIRA, A. G.; CAVALCANTE, R. M.; FECHINE, P. B. A.; SOUSA NETO, V. O.; DE KEUKELEIRE, D.; NASCIMENTO, R. F. Evaluation of a low-cost adsorbent for removal of toxic metal ions from wastewater of an electroplating factory J. Environ. Manage. 2009, 89, 1-5.

Como citar:

MELO, D. Q.; OLIVEIRA1, J. T.; TEIXEIRA, R. N. P.; NASCIMENTO, R. F.; Giselle Santiago Cabral Raulino; Carla Bastos; "Use of fractional factorial design for optimizing removal of nickel, copper, cadmium and lead by buriti modified fibers", p-8383-8390. In: Anais do XX Congresso Brasileiro de Engenharia Química - COBEQ 2014 [= Blucher Chemical Engineering Proceedings, v.1, n.2]. São Paulo: Blucher, 2015.
ISSN 23591757, DOI 10.5151/chemeng-cobeq2014-1232-20357-170225