Synthesis of novel phosphinamide phosphoramidate conjugates with possible applications in catalysis

Synthesis of novel phosphinamide phosphoramidate conjugates with possible applications in catalysis

Medeiros, Antonia Carlene R. F.; Bernardino, Alice Maria R.; Souza, Marcos C. de; Ortiz, Fernando L.

Abstract:

This work aims to extend the chemistry of phosphinamides ortho lithiated and phosphoramidates, leading to the new derivatives 6a-e and 7a-e in order to investigate their usefulness as ligands di-, tri- and tetradentate towards Y3+ and lanthanides (La3+, Sm3+ and Eu3+), as well as the application in catalysis.

This work aims to extend the chemistry of phosphinamides ortho lithiated and phosphoramidates, leading to the new derivatives 6a-e and 7a-e in order to investigate their usefulness as ligands di-, tri- and tetradentate towards Y3+ and lanthanides (La3+, Sm3+ and Eu3+), as well as the application in catalysis.

Palavras-chave:

DOI: 10.5151/chempro-15bmos-BMOS2013_2013819201137

Referências bibliográficas

• [1] 1 Popovici, C.; Oña Burgos, P.; Fernández, I.; Roces, L.; García
• [2] Granda, S.; Iglesias, M. J.; López Ortiz, F. Org. Lett. 2010, 12,
• [3] 428.
• [4] 2 Yang, C.; Cheung, Y, K.; Wong, Y, T.; Jia, G, Organometallics,
• [5] 2001, 20, 424-429.
• [6] 3 Cabral, S.; Hulin, B.; Kawai, M, Tetrahedron Letters 2007, 48,
• [7] 7134–7136.

Como citar:

Medeiros, Antonia Carlene R. F.; Bernardino, Alice Maria R.; Souza, Marcos C. de; Ortiz, Fernando L.; "Synthesis of novel phosphinamide phosphoramidate conjugates with possible applications in catalysis", p-180-180. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-15bmos-BMOS2013_2013819201137