Synthesis and photophysical properties of a Tröger’s basetriazole- linked glycoconjugate

Synthesis and photophysical properties of a Tröger’s basetriazole- linked glycoconjugate

Pimentel, Débora M.; Vargas, Jaqueline P.; Lüdtke, Diogo S.; Rodembusch, Fabiano S.

Abstract:

Tröger’s base is a chiral amine discovered by Julius Tröger in 1877, which exists as two enantiomers. Its intrinsic concavity and rigid structure can provide several applications. On the other hand, carbohydrates are the most abundant renewable resource in the planet, and they have interesting applications. Additionally, an efficient way of connecting a carbohydrate to a Tröger’s base framework is a 1,3-dipolar cycloaddition reaction - “Click Chemistry”. In this way, we present the synthesis and photophysical characterization of a new Tröger’s base analogue containing a carbohydrate as ring substituent.

Tröger’s base is a chiral amine discovered by Julius Tröger in 1877, which exists as two enantiomers. Its intrinsic concavity and rigid structure can provide several applications. On the other hand, carbohydrates are the most abundant renewable resource in the planet, and they have interesting applications. Additionally, an efficient way of connecting a carbohydrate to a Tröger’s base framework is a 1,3-dipolar cycloaddition reaction - “Click Chemistry”. In this way, we present the synthesis and photophysical characterization of a new Tröger’s base analogue containing a carbohydrate as ring substituent.

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DOI: 10.5151/chempro-15bmos-BMOS2013_2013823103143

Referências bibliográficas

• [1] 1 Tröger, J. J. Prakt. Chem. 1877, 36, 225.
• [2] 2 Rúnarsson, O. V.; Artacho, J. e Wärnmark, K. Eur. J. Org. Chem. 2012, 7015.
• [3] 3 Levy, D. E..; Fügedi, P., Eds. The Organic Chemistry of Sugars, CRC Press, Boca Ratón, 2006.

Como citar:

Pimentel, Débora M.; Vargas, Jaqueline P.; Lüdtke, Diogo S.; Rodembusch, Fabiano S.; "Synthesis and photophysical properties of a Tröger’s basetriazole- linked glycoconjugate", p-201-201. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-15bmos-BMOS2013_2013823103143