Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013
Abstract - Open Access.
Exploring the enantioselective Heck-Matsuda reaction with electron-rich endocyclic olefins – 2,3-dihydrofuran asymmetric arylation
Schwalm, Cristiane Storck ; Correia, Carlos Roque Duarte ;
Abstract:
The Heck reaction is a powerful tool for C-C bond formation, being widely used in the modern organic synthesis. The Heck-Matsuda reaction (HM), which employs arenediazonium salts as arylating agents, is gaining increasing prominence, requiring milder reaction conditions and simpler experimental procedures. Recently, our research group reported the first example of the enantioselective HM reaction employing chiral bis-oxazoline ligands. We present herein studies aiming at the enantioselective arylation of 2,3-DHF, a cyclic activated olefin.
Abstract:
Palavras-chave: enantioselective Heck-Matsuda, 2,3-dihydrofuran, N,N-ligands,
Palavras-chave:
DOI: 10.5151/chempro-15bmos-BMOS2013_20139720518
Referências bibliográficas
- [1] 1 Taylor, J. G.; Moro, A. V.; Correia, C. R. D. Eur. J. Org. Chem. 2011, 1403-1428.
- [2] 2 Correia, C. R. D.; Oliveira, C. C.; Salles Jr., A. G.; Santos, E. A. F. Tetrahedron Lett. 2012, 53, 3325-3328.
Como citar:
Schwalm, Cristiane Storck; Correia, Carlos Roque Duarte; "Exploring the enantioselective Heck-Matsuda reaction with electron-rich endocyclic olefins – 2,3-dihydrofuran asymmetric arylation", p. 24 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013.
São Paulo: Blucher,
2013.
ISSN 2318-4043,
DOI 10.5151/chempro-15bmos-BMOS2013_20139720518
últimos 30 dias | último ano | desde a publicação
downloads
visualizações
indexações