Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

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Catalysis and mechanistic investigation with ionically-tagged reagents

Neto, B. A. D. ;

Abstract:

This flash presentation focus on the concept, development, synthesis and application of new ionically-tagged catalysts applied for cross-coupling, multicomponent reactions, oxidation and reduction reactions. The ionic tags are responsible for the nanoorganisation and nano- effect observed for those new catalysts. The presence of at least one ionic tag allows the direct investigation of the reactions mechanisms via electrospray (tandem) mass spectrometry - ESI-MS(/MS) - with important implications for the biomimetic transformations compared with the enzymatic ones (e.g. Cytochrome P-450 oxidation). The catalysts could be recycled and reused for several times without any notable loss of catalytic activity.

Abstract:

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Palavras-chave: ionically-tagged catalysts, biomimetic transformations, ESI-MS(/MS),

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DOI: 10.5151/chempro-15bmos-1-template_Speech_15th_BMOS-neto

Referências bibliográficas
  • [1] 1 Curtis, M. D.; Shiu, K.; Butler, W. M. e Huffmann, J. C. J. Am. Chem. Soc. 1986, 108, 3335.
  • [2] 2 Curtis, M. D.; Shiu, K.; Butler, W. M. e Huffmann, J. C. J. Am. Chem. Soc. 1986, 108, 3335.
Como citar:

Neto, B. A. D.; "Catalysis and mechanistic investigation with ionically-tagged reagents", p. 311 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-1-template_Speech_15th_BMOS-neto

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