Asymmetric Ring Contraction Reactions Mediated by Chiral I(III)

Asymmetric Ring Contraction Reactions Mediated by Chiral I(III)

Ahmad, Anees; Silva, Luiz F.; Jr.

Abstract:

Hypervalent iodine reagents are widely used in chemical synthesis. The development of reaction processes controlled by chiral hypervalent iodine reagents with high enantioselectivity has drawn extensive and enduring attention because of their environmentally friendly profile and avoids the issue of toxicity. Rearrangement reaction is one of the important reactions promoted by I(III). Herein, we describe asymmetric ring contraction reactions mediated by chiral hypervalent iodine reagents.

Hypervalent iodine reagents are widely used in chemical synthesis. The development of reaction processes controlled by chiral hypervalent iodine reagents with high enantioselectivity has drawn extensive and enduring attention because of their environmentally friendly profile and avoids the issue of toxicity. Rearrangement reaction is one of the important reactions promoted by I(III). Herein, we describe asymmetric ring contraction reactions mediated by chiral hypervalent iodine reagents.

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DOI: 10.5151/chempro-15bmos-BMOS2013_201398181055

Referências bibliográficas

• [1] 1 Silva, L. F., Jr.; Olofsson, B. Nat. Prod. Rep. 2011, 28, 1722.
• [2] 2 Liang, H.; Ciufolini, M. A. Angew. Chem. Int. Ed. 2011, 50, 11849.
• [3] 3 Farid, U.; Malmedy, F.; Claveau, R.; Albers, L.; Wirth, T. Angew. Chem. Int. Ed. 2013, 52, 7018.
• [4] 4 Silva, L. F., Jr.; Siqueira, F. A.; Pedrozo, E. C.; Vieira, F. Y. M.; Doriguetto, A. C. Org. Lett. 2007, 9, 1433.

Como citar:

Ahmad, Anees; Silva, Luiz F.; Jr., ; "Asymmetric Ring Contraction Reactions Mediated by Chiral I(III)", p-119-119. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-15bmos-BMOS2013_201398181055