An efficient and reusable palladium nanocatalyst in C-C bond forming cross-coupling reactions

An efficient and reusable palladium nanocatalyst in C-C bond forming cross-coupling reactions

Ganapathy, D.; Sekar, G.

Abstract:

Palladium catalysts have been extensively studied in the synthetic organic chemistry particularly in C-C bond forming cross-coupling reactions. Alternatively, palladium nanoparticles (Pd NPs) have attracted a remarkable interest in organic synthesis owing to the enhanced catalytic reactivity and lower catalytic loading. Traditional stabilizers such as phosphines, amines and dendrimers are used for the preparation of NPs which often leads to agglomerization of NPs during the catalytic reaction. The Pd NPs stabilized by Pd-C covalent bond are much more stable than the traditional stabilizers.

Palladium catalysts have been extensively studied in the synthetic organic chemistry particularly in C-C bond forming cross-coupling reactions. Alternatively, palladium nanoparticles (Pd NPs) have attracted a remarkable interest in organic synthesis owing to the enhanced catalytic reactivity and lower catalytic loading. Traditional stabilizers such as phosphines, amines and dendrimers are used for the preparation of NPs which often leads to agglomerization of NPs during the catalytic reaction. The Pd NPs stabilized by Pd-C covalent bond are much more stable than the traditional stabilizers.

Palavras-chave:

DOI: 10.5151/chempro-15bmos-BMOS2013_201386477

Referências bibliográficas

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• [3] 3 Ghosh, D.; Chen, S. J. Mater. Chem. 2008, 18, 755.
• [4] 4Ganapathy, D.; Sekar, G. Catal. Commun. 2013, 39, 50.

Como citar:

Ganapathy, D.; Sekar, G.; "An efficient and reusable palladium nanocatalyst in C-C bond forming cross-coupling reactions", p-1-1. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-15bmos-BMOS2013_201386477