Blucher Chemical Engineering Proceedings
- Todas as edições
- Última edição
- Equipe de Produção
- ISSN 2359-1757
ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS
ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS
ZARANTE, P. B.; COSTA, T.; SODRÉ, J. R.
Artigo:
This paper presents a mathematical model which calculates aldehyde emissions in the exhaust of a spark ignition engine fueled with ethanol. The numerical model for aldehyde emissions was developed using FORTRAN software, with input data obtained from the engine cycle simulated by the commercial software BOOST. The model calculates formaldehyde and acetaldehyde emissions, formed from the partial oxidation of methane, ethane and unburned ethanol. The calculated values were compared with experimental data obtained by Fourier Transform Infrared Spectroscopy (FTIR). Tests were performed with a mid-size sedan powered by 1.4-liter spark ignition engine on a chassis dynamometer. In general, the results demonstrate that the concentrations of aldehydes and their producers increased with engine speed and exhaust gas temperature. There was a good agreement between simulated and measured values.
This paper presents a mathematical model which calculates aldehyde emissions in the exhaust of a spark ignition engine fueled with ethanol. The numerical model for aldehyde emissions was developed using FORTRAN software, with input data obtained from the engine cycle simulated by the commercial software BOOST. The model calculates formaldehyde and acetaldehyde emissions, formed from the partial oxidation of methane, ethane and unburned ethanol. The calculated values were compared with experimental data obtained by Fourier Transform Infrared Spectroscopy (FTIR). Tests were performed with a mid-size sedan powered by 1.4-liter spark ignition engine on a chassis dynamometer. In general, the results demonstrate that the concentrations of aldehydes and their producers increased with engine speed and exhaust gas temperature. There was a good agreement between simulated and measured values.
Palavras-chave:
DOI: 10.5151/chemeng-cobeq2014-0831-23477-135095
Referências bibliográficas
- [1] AMARAL, R.A.; SODRÉ J.R. Aldehyde emissions from an ethanol-fuelled vehicle as influenced by engine geometric parameters. SAE Technical Paper 2001-01-1998.
- [2] Society of Automotive Engineers, USA. 2001.
- [3] AMARAL, R.A.; SODRÉ, J.R.; Influence of engine operating parameters on aldehyde emissions from an ethanol-fuelled vehicle. Combust. Sci. Technol., v. 174, p. 153-65, 2002.
- [4] BASSHUYSEN, R.; SCHÄFER, F. Internal Combustion Engine Handbook: Basics, Components, Systems, and Perspectives. Warrendale: SAE International, 2004.
- [5] COSTA, T.O.; ZARANTE, P.H.B.; SODRÉ, J.R. Simulation of aldehyde formation in ethanol fuelled spark ignition engines, In: Sens M, Baar R, editors. Engine processes, Renningen: Expert Verlag. p. 112-122, 2013.
- [6] CHEUNG, C.S.; DI, Y.; HUANG, Z. Experimental investigation of regulated and unregulated emissions from a diesel engine fueled with ultralow-sulfur diesel fuel blended with ethanol and dodecanol. Atmos. Environ., v. 42, p. 8843-51, 2008.
- [7] DAUSTER, I. Chemical kinetics of ethanol oxidation and pyrolysis. COST - Detailed chemical models for cleaner combustion, 1st Annual Meeting, Sept. 15-16, 2010.
- [8] FRASSOLDATI, A.; CUOCI, A.; FARAVELLI, T.; NIEMANN, U.; RANZI, E.; SEISER, R.; SESHADRI, K. An experimental and kinetic modeling study of n-propanol and iso-propanol combustion. Combust. Flame,. v. 157, p. 2-16, 2010.
- [9] HE, B-Q.; SHUAI, S-J.; WANG, J-X.; HE, H. The effect of ethanol blended diesel fuels on emissions from a diesel engine. Atmos. Environ. v. 37, p. 4965-71, 2003.
- [10] KEATING, E.L. Applied Combustion. New York: Marcel Dekker, 1993.
- [11] LI, J.; KAZAKOV, A.; CHAOS, M.; DRYER, F.L. Chemical kinetics of ethanol oxidation. 5th US Combustion Meeting, Paper #C26, March 25-28, 2007.
- [12] MAGNUSSON, S.; NILSSON, C. The influence of oxygenated fuels on emissions of aldehydes and ketones from a two-stroke spark ignition engine. Fuel, v. 90, p. 1145-54, 2011.
- [13] Área temática: Engenharia Ambiental e Tecnologias Limpas 7MARINOV, N. A detailed chemical kinetic model for high temperature ethanol oxidation. Int. J. Chem. Kinetics, v. 31, p. 183-220, 1998.
- [14] MERRIT, P.M.; ULMET, V.; McCORMICK, R.L.; MITCHELL, W.E.; BAUGMARD, K.J. Regulated and unregulated exhaust emissions comparison for three Tier II non-road diesel engines operating on ethanol-diesel blends. SAE Technical Paper 2005-01-2193., Society of Automotive Engineers, USA; 2005.
- [15] NGUYEN, H.T-H.; TAKENAKA, N.; BANDOW, H.; MAEDA, Y.; DE OLIVA, S.; BOTELHO, M.; TAVARES, T. Atmospheric alcohols and aldehydes concentrations measured in Osaka, Japan and in São Paulo, Brazil. Atmos. Environ., v. 35, p. 3075-83, 2001.
- [16] PANG, X.; UM, Y.; YUAN, J.; HE, H.; Carbonyls emission from ethanol-blended gasoline and biodiesel-ethanol-diesel used in engines. Atmos. Environ., 2008;42:1349-58.
- [17] SONG, C.; ZHAO, Z.; LIV, G.; SONG, J.; LIU, L.; ZHAO, R. Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend. Chemosphere, v. 79, p. 1033-39, 2010.
Como citar:
ZARANTE, P. B.; COSTA, T.; SODRÉ, J. R.; "ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS", p-7738-7745.
In: Anais do XX Congresso Brasileiro de Engenharia Química - COBEQ 2014 [= Blucher Chemical Engineering Proceedings, v.1, n.2].
São Paulo: Blucher,
2015.
ISSN 23591757,
DOI 10.5151/chemeng-cobeq2014-0831-23477-135095
últimos 30 dias
102
downloads
325
visualizações
1480
indexações
Sou autor desse trabalho
Você é citado neste trabalho?
Exportar citação - RefWork (RIS)
Copie a citação abaixo ou clique no botão Download para obter um arquivo com os dados
TY - CONF T1 - ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS JO - Blucher Chemical Engineering Proceedings VL - 1 IS - 2 SP - 7738 EP - 7745 PY - 2015 T2 - XX Congresso Brasileiro de Engenharia Química AU - , , SN - 23591757 DO - http://dx.doi.org/10.5151/chemeng-cobeq2014-0831-23477-135095 UR - www.proceedings.blucher.com.br/article-details/aldehyde-emissions-from-an-ethanol-fuelled-spark-ignition-engine-simulation-and-ftir-measurements-17602 KW - ER -
Exportar citação - BibTeX(BIB)
Copie a citação abaixo ou clique no botão Download para obter um arquivo com os dados
@article{ZARANTE20144,
title="ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS",
journal="Blucher Chemical Engineering Proceedings",
volume="1",
number="2",
pages="7738 - 7745",
year="2015",
note="",
issn="23591757",
doi="http://dx.doi.org/10.5151/chemeng-cobeq2014-0831-23477-135095",
url="www.proceedings.blucher.com.br/article-details/aldehyde-emissions-from-an-ethanol-fuelled-spark-ignition-engine-simulation-and-ftir-measurements-17602",
author="P. B. ZARANTE", "T. COSTA", "J. R. SODRÉ",
keywords="",
}
Exportar citação - Text(TXT)
Copie a citação abaixo ou clique no botão Download para obter um arquivo com os dados
P. B. ZARANTE, T. COSTA, J. R. SODRÉ, ALDEHYDE EMISSIONS FROM AN ETHANOL-FUELLED SPARK IGNITION ENGINE: SIMULATION AND FTIR MEASUREMENTS, Blucher Chemical Engineering Proceedings, Volume 1, 2015, Pages 7738-7745, ISSN 23591757, http://dx.doi.org/10.5151/chemeng-cobeq2014-0831-23477-135095 (www.proceedings.blucher.com.br/article-details/aldehyde-emissions-from-an-ethanol-fuelled-spark-ignition-engine-simulation-and-ftir-measurements-17602) Palavras-chave:: ;