janeiro 2015 vol. 1 num. 3 - International Symposium on Crystallography
Abstract - Open Access.
SYNTHESIS STUDY OF MAGNETIC PROPERTIES AND GIANT MAGNETOIMPEDANCE IN MANGANITES NANOCRYSTALLINE La0.7Ba0.3-XSrXMnO3
Recent studies reported in the literature have shown that nanocrystalline manganites may have the effect of giant magnetoimpedance (GMI). The GMI effect was observed in the region reaching the radiofrequency values of up to 70% at room temperature in less than 1 kOe magnetic field. Due to these characteristics, manganite may be applied to the development of magnetic sensors. In this work, we present a study of magnetic materials with nanometric manganites La0.7Ba0.3-xSrxMnO3 (0 ≤ x ≤ 0.3) varying the concentration of Ba and Sr. In the chemical synthesis process, we use the technique of reaction by ion coordination, setting the corresponding stoichiometric proportions of each compound. The samples were compacted in tablet form and synthesized to 1150 0C for 10 h in an atmosphere of O2. Analysis of X-ray diffraction (XRD) showed the formation of a polycrystalline phase with pure orthorhombic perovskite structure and space group Pbnm: cab. Through Rietveld refinements of X-ray powder diffraction patterns of samples, we obtained average particle diameters around 100 nm. Magnetic measurements as a function of temperature with Zero-Field-Cooling (ZFC) and Field-Cooling (FC) were made using a vibrating sample magnetometer. Magnetic hysteresis cycles at room temperature showed that the samples have: low coercivity and saturation magnetization to the maximum around 73 emu/g for Sample La0.7Ba0.3MnO3. Scanning electronic microscopy images (SEM) of the La0.7Ba0.3MnO3 pellet detailing the size and shape of the particles is influenced by different pressures applied on the material in the compaction. Electrical impedance measurements as a function of frequency and magnetic field will also be presented.
da Silva, R. B.; de Góis, M. M.; de Freitas, C. R. D.; Soares, J. M.; "SYNTHESIS STUDY OF MAGNETIC PROPERTIES AND GIANT MAGNETOIMPEDANCE IN MANGANITES NANOCRYSTALLINE La0.7Ba0.3-XSrXMnO3", p. 84 . In: Proceedings of the International Symposium on Crystallography [Blucher Physics Proceedings, v.1, n.3].
São Paulo: Blucher,
ISSN 2358-2359, DOI 10.5151/phypro-sic100-084
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