fevereiro 2015 vol. 1 num. 2 - XX Congresso Brasileiro de Engenharia Química

Artigo - Open Access.

Idioma principal

PHOTO-FENTON AND ADSORPTION COMBINED PROCESS FOR DEGRADATION AND REMOVING OF COOMASSIE BRILLIANT BLUE DYE FROM AQUEOUS SOLUTION

CANTELI, A. M. D.; CARPINE, D.; DONÁ, G.; TAKASHINA, T. A.; SCHEER, A. de P.; IGARASHI-MAFRA, L.;

Artigo:

RESUME – Coomassie Brilliant Blue (CBB) is a commonly dye present in the waste of the textile industry. Its use produces waste which must be treated before being discharged into rivers or sewage. Combined processes have been used with efficiency for wastewater treatment. This study aims to evaluate the combined process of photo-Fenton and adsorption for the degradation and removal of the dye CBB in aqueous solution. Initially, the CBB was submitted to photo-Fenton oxidation. Photo-Fenton oxidation degraded 76,9% of the initial CBB concentration, which was not enough to satisfies the Brazilian legislation. The fixed-bed adsorption was conducted for 13 hours, and during all this period the outlet concentration was always lower than the breakpoint, being this concentration in compliance with the legislation. The combined photo-Fenton/Fixed-bed adsorption was effective in the CBB removing (at least 95,9%). Keywords: Fixed bed; granular activated carbon; waste treatment; combined treatment;

Artigo:

Palavras-chave:

DOI: 10.5151/chemeng-cobeq2014-0611-24728-147356

Referências bibliográficas
  • [1] AKSU, Z.; GÖNEN, F. Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves. Process biochem., v. 39 p. 599-613, 2004.
  • [2] ALMAZÁN-SÁNCHEZ, P. T.; LINARES-HERNÁNDEZ, I.; MARTÍNEZ-MIRANDA, V.; LUGO-LUGO, V.; OCA, R. M. G. F.-M. de. Wastewater treatment of methyl methacrylate (MMA) by Fenton''s reagent and adsorption. Catal. today. v. 220-222, p. 39-48, 2014.
  • [3] BUKALLAH, S. B.; RAUF, M. A.; ASHRAF, S. S. Photocatalytic decoloration of Coomassie Brilliant Blue with titanium oxide. Dyes Pigm. v. 72, p. 353-356, 2007.
  • [4] CAIXETA, F. J.; SANTOS, D. V. D.; PIMENTA, A. C.; LEAL, R. C.; RAZABONI, A. M. Degradação de Corante Coomassie® Brilliant Blue em Resíduos Gerados em Laboratórios de Ensino e Pesquisa, via Processo foto-Fenton. In: 36ª Reunião Anual da Sociedade Brasileira de Química. Águas de Lindóia – São Paulo, 2013.
  • [5] CONAMA, RESOLUÇÃO N° 430, DE 13 DE MAIO DE 2011. Available in: Andlt;http://www.mma.gov.br/port/conama/legiabre.cfm?codlegi=646Andgt;. Accessed on: 20/04/2014.
  • [6] HAN, R.; WANG, Y.; ZHAO, X.; WANG, Y.; XIE, F.; CHENG, J.; TANG, M. Adsorption of methylene blue by phoenix tree leaf powder in a fixed-bed column: experiments and prediction of breakthrough curves. Desalination. v. 245, p. 284-297, 2009.
  • [7] IGARASHI-MAFRA, L.; BORTOLETTO , E. C.; BARROS, M. A. S. D.; SORBO, A. C. A. C.; GALLIANI, N. A.; TAVARES, C. R. G. Degradation of Odontologic X-Ray Film Developing Wastewaters by Photo-Fenton Process. Int. j. chem. react. eng. v. 5, 200
  • [8] LUCAS, M. S.; PERES J. A. Decolorization of the azo dye Reactive Black 5 by Fenton and photo-Fenton oxidation. Dyes Pigm. v. 71, p. 236-244, 2006.
  • [9] RAMÍREZ-SOSA, D. R.; CASTILLO-BORGES, E. R.; MÉNDEZ-NOVELO, R. I.; SAURI-RIANCHO, M. R.; BARCELÓ-QUINTAL, M.;MARRUFO-GÓMEZ, J. M. Determination of organic compounds in landfill leachates treated by Fenton–Adsorption. Waste Manag. v. 33, p. 390-395, 2013.
  • [10] RAUF, M. A.; ASHRAF, S.; ALHADRAMI, S. N. Photolytic oxidation of Coomassie Brilliant Blue with H2O2. Dyes Pigm. v. 66, p. 197-200, 2005.
  • [11] RAUF, M. A.; BUKALLAH, S. B.; HAMOUR, F. A.; NASIR, A. S. Adsorption of dyes from aqueous solutions onto sand and their kinetic behavior. Chem. eng. j. v. 137, p. 238-243, 2008.
  • [12] SALDAÑA-ROBLES, A.; GUERRA-SÁNCHEZ, R.; MALDONADO-RUBIO, M. I.; PERALTA-HERNÁNDEZ, J. M. Optimization of the operating parameters using RSM for the Fenton oxidation process and adsorption on vegetal carbon of MO solutions. J. ind. eng. chem. v. 20, p. 848-857, 2014.
  • [13] SALES, P. F. de; MAGRIOTIS, Z. M.; ROSSI, M. A. L. S.; RESENDE, R. F.; NUNES, C. A. Optimization by Response Surface Methodology of the adsorption of Coomassie Blue dye Área temática: Engenharia Ambiental e Tecnologias Limpas 7on natural and acid-treated clays. J. environ. Manag. v. 130, p. 417-428, 20
  • [14] THANKAPPAN, R.; NGUYEN, T. V.; SRINIVASAN, S. V.; VIGNESWARAN, S.; KANDASAMY, J.; LOGANATHAN, P. Removal of leather tanning agent syntan from aqueous solution using Fenton oxidation followed by GAC adsorption. J. ind. eng. chem. Article in press. 20
  • [15] WANG, S.; NG, C. W.; WANG, W.; LI, Q.; HAO, Z. Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes. Chem. eng. j. v. 197, p. 34-40, 2012.
Como citar:

CANTELI, A. M. D.; CARPINE, D.; DONÁ, G.; TAKASHINA, T. A.; SCHEER, A. de P.; IGARASHI-MAFRA, L.; "PHOTO-FENTON AND ADSORPTION COMBINED PROCESS FOR DEGRADATION AND REMOVING OF COOMASSIE BRILLIANT BLUE DYE FROM AQUEOUS SOLUTION", p. 7362-7369 . In: Anais do XX Congresso Brasileiro de Engenharia Química - COBEQ 2014 [= Blucher Chemical Engineering Proceedings, v.1, n.2]. São Paulo: Blucher, 2015.
ISSN 2359-1757, DOI 10.5151/chemeng-cobeq2014-0611-24728-147356

últimos 30 dias | último ano | desde a publicação


downloads


visualizações


indexações