Full article - Open Access.

Idioma principal | Segundo idioma

USE OF MELT FLOW INDEX MEASUREMENTS TO EVALUATE THE RHEOLOGICAL PROPERTIES OF POLYBUTYLENE SUCCINATE (PBS) WHEN SUBMITTED TO DRYING

USE OF MELT FLOW INDEX MEASUREMENTS TO EVALUATE THE RHEOLOGICAL PROPERTIES OF POLYBUTYLENE SUCCINATE (PBS) WHEN SUBMITTED TO DRYING

AZEVEDO, JOYCE BATISTA ; Almeida, Ilana Oliveira ; Horiuchi, Lucas Nao ; Fialho, Rosana Lopes Lima ;

Full article:

Polybutylene succinate (PBS) is a biodegradable polymer that has the potential to replace conventional plastic, however it has limitations such as processing viscosity and high cost. In this work, melt flow index index (MFR) measurements were used to evaluate the influence of the way PBS was packaged before processing and whether this condition could influence the rheological characteristics of the polymer. For this purpose, samples of PBS packaged by the manufacturer (humid PBS) and after drying for 5 hours at 70°C (dry PBS) were evaluated. The results confirmed the degradation condition of the PBS, before being submitted to drying, since the MFR of the sample presented a reduction of 75% of the value indicated by the manufacturer. The melt flow index, obtained from the variation in weight, was used to evaluate the rheological curve of the PBS and a pseudoplastic behavior was verified that did not vary with the form of packaging.

Full article:

Polybutylene succinate (PBS) is a biodegradable polymer that has the potential to replace conventional plastic, however it has limitations such as processing viscosity and high cost. In this work, melt flow index index (MFR) measurements were used to evaluate the influence of the way PBS was packaged before processing and whether this condition could influence the rheological characteristics of the polymer. For this purpose, samples of PBS packaged by the manufacturer (humid PBS) and after drying for 5 hours at 70°C (dry PBS) were evaluated. The results confirmed the degradation condition of the PBS, before being submitted to drying, since the MFR of the sample presented a reduction of 75% of the value indicated by the manufacturer. The melt flow index, obtained from the variation in weight, was used to evaluate the rheological curve of the PBS and a pseudoplastic behavior was verified that did not vary with the form of packaging.

Palavras-chave: Polybutylene succinate, Melt Flow Index, Drying,

Palavras-chave: Polybutylene succinate, Melt Flow Index, Drying,

DOI: 10.5151/siintec2023-306783

Referências bibliográficas
  • [1] " SAMIR, Aya et al. Recent advances in biodegradable polymers for sustainable
  • [2] applications. Npj Materials Degradation, v. 6, n. 1, p. 68, 202 LUCKACHAN, Gisha E.; PILLAI, C. K. S. Biodegradable polymers-a review on
  • [3] recent trends and emerging perspectives. Journal of Polymers and the
  • [4] Environment, v. 19, p. 637-676, 2011.
  • [5] 3. DI LORENZO, Maria Laura; ANDROSCH, René; RIGHETTI, Maria Cristina.
  • [6] Low-temperature crystallization of poly (butylene succinate). European Polymer
  • [7] Journal, v. 94, p. 384-391, 201
  • [8] 4. RAFIQAH, S. Ayu et al. A review on properties and application of bio-based poly
  • [9] (butylene succinate). Polymers, v. 13, n. 9, p. 1436, 2021.
  • [10] 5. PHUA, Y. J.; CHOW, W. S.; MOHD ISHAK, Z. A. Mechanical properties and
  • [11] structure development in poly (butylene succinate)/organo-montmorillonite
  • [12] nanocomposites under uniaxial cold rolling. Express Polymer Letters, v. 5, n. 2,
  • [13] 2011.
  • [14] 6. MANRICH, Silvio. Processamento de Termoplásticos: rosca única, extrusão e
  • [15] matrizes, injeção e moldes. Artliber Ed., 2005.
  • [16] 7. SCHRAMM, Gebhard. Reologia e reometria: fundamentos teóricos e práticos.
  • [17] Artliber Ed., 2006.
  • [18] 8. CANEDO, Eduardo Luís. Fenômenos de transporte. Grupo Gen-LTC, 2000.
  • [19] 9. HAN, Chang Dae. Rheology and processing of polymeric materials: Volume 1:
  • [20] Polymer Rheology. Oxford University Press, 2007.
  • [21] 10.Technical Data Sheet, BioPBS™ FZ71PM.
  • [22] 11.ADAMOPOULOU, Eirini. Poly (butylene succinate): A promising biopolymer.
  • [23] 2013. Tese de Doutorado. University of Piraeus (Greece).
  • [24] 12.CANEDO, Eduardo Luís. Fenômenos de transporte. Grupo Gen-LTC, 2000.
  • [25] 13.RAUWENDAAL, Chris. Extrusion. Encyclopedia of Polymer Science and
  • [26] Technology, v. 2, 2002.
  • [27] 14.DE PAOLI, Marco Aurelio. Degradação e estabilização de polímeros. 2009.
  • [28] 15.MUTHURAJ, Rajendran; MISRA, Manjusri; MOHANTY, A. K. Hydrolytic
  • [29] degradation of biodegradable polyesters under simulated environmental
  • [30] conditions. Journal of Applied Polymer Science, v. 132, n. 27, 2015.
  • [31] 16.SCHRAMM, Gebhard. Reologia e reometria: fundamentos teóricos e práticos.
  • [32] Artliber Ed., 2006."
Como citar:

AZEVEDO, JOYCE BATISTA ; Almeida, Ilana Oliveira ; Horiuchi, Lucas Nao ; Fialho, Rosana Lopes Lima ; "USE OF MELT FLOW INDEX MEASUREMENTS TO EVALUATE THE RHEOLOGICAL PROPERTIES OF POLYBUTYLENE SUCCINATE (PBS) WHEN SUBMITTED TO DRYING", p. 579-585 . In: . São Paulo: Blucher, 2023.
ISSN 2357-7592, DOI 10.5151/siintec2023-306783

últimos 30 dias | último ano | desde a publicação


downloads


visualizações


indexações