The Diels-Alder reactions of carbomethoxy-p-benzoquinones with simple dienes

The Diels-Alder reactions of carbomethoxy-p-benzoquinones with simple dienes

Donatoni, Maria Carolina; Brocksom, Timothy John; Uliana, Marciana P.; Oliveira, Kleber T. de

Abstract:

The Diels-Alder reactions of p-benzoquinones and derivatives with simple dienes provide functionalized cycloadducts that can be employed in the synthesis of bioactive terpenes. We now present our results on the Diels-Alder reactions of carbomethoxy-pbenzoquinones with simple dienes, performed at room temperature, with Lewis acid catalysis, and with microwave irradiation.

The Diels-Alder reactions of p-benzoquinones and derivatives with simple dienes provide functionalized cycloadducts that can be employed in the synthesis of bioactive terpenes. We now present our results on the Diels-Alder reactions of carbomethoxy-pbenzoquinones with simple dienes, performed at room temperature, with Lewis acid catalysis, and with microwave irradiation.

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DOI: 10.5151/chempro-14bmos-R0197-1

Referências bibliográficas

• [1] 1 Brocksom, T. J.; et. al. “Diels-Alder Reactions in the Synthesis of Higher Terpenes,” in Organic Synthesis: Theory and Applications, T. Hudlicky (ed). JAI/Elsevier, Vol. 5, 39-87, 2001.
• [2] 2 Brocksom, T. J.; Brocksom, U.; Nakamura, J.; Ferreira, M. L. J. Braz. Chem. Soc. 2001, 12, 597.
• [3] 3 Brocksom, T. J.; Donatoni, M. C.; Uliana, M. P.; Vieira, Y. W.; Quim. Nova, 2010, 33, 2211.

Como citar:

Donatoni, Maria Carolina; Brocksom, Timothy John; Uliana, Marciana P.; Oliveira, Kleber T. de; "The Diels-Alder reactions of carbomethoxy-p-benzoquinones with simple dienes", p-197-197. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0197-1