Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

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Synthesis of novel optically active ligants to coordination chemistry and its application in the organic reactions

Toledo, P. R. S. ; Oliveira, D. M. ; Ferreira, J. G. ; Leotério, D. M. S. ; Alves Jr, S. ; Princival, J. L. ;

Abstract:

Coordination compounds containing 2-oxazoline unit can be applied as catalysts in organic reactions. Moreover, few studies related to the use of oxazoline-lanthanide complexes in organic reactions are described. Here we will present the preparation of new ligands containing oxazoline function and the use of these compounds in the preparation of a new class of lanthanides and other coordination compounds. Our initial studies on the application of these catalysts have been made in the epoxide opening reaction.

Abstract:

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Palavras-chave: catalyst, chiral complexes, lanthanides,

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DOI: 10.5151/chempro-14bmos-R0368-1

Referências bibliográficas
  • [1] 1 Evans, D. A.; Miller, S. J.; Lectka, T. J. Am. Chem. Soc. 1993, 115, 6460.
  • [2] 2 (a) Molander, G. A.; Hahn, G. J. Org. Chem. 1986, 51, 2596; (b) Schaus, S. E.; Jacobsen, E. N. Org. Lett. 2000, 2, 1001.
Como citar:

Toledo, P. R. S.; Oliveira, D. M.; Ferreira, J. G.; Leotério, D. M. S.; Alves Jr, S.; Princival, J. L.; "Synthesis of novel optically active ligants to coordination chemistry and its application in the organic reactions", p. 368 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0368-1

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