Synthesis of novel optically active ligants to coordination chemistry and its application in the organic reactions

Synthesis of novel optically active ligants to coordination chemistry and its application in the organic reactions

Toledo, P. R. S.; Oliveira, D. M.; Ferreira, J. G.; Leotério, D. M. S.; Alves Jr, S.; Princival, J. L.

Abstract:

Coordination compounds containing 2-oxazoline unit can be applied as catalysts in organic reactions. Moreover, few studies related to the use of oxazoline-lanthanide complexes in organic reactions are described. Here we will present the preparation of new ligands containing oxazoline function and the use of these compounds in the preparation of a new class of lanthanides and other coordination compounds. Our initial studies on the application of these catalysts have been made in the epoxide opening reaction.

Coordination compounds containing 2-oxazoline unit can be applied as catalysts in organic reactions. Moreover, few studies related to the use of oxazoline-lanthanide complexes in organic reactions are described. Here we will present the preparation of new ligands containing oxazoline function and the use of these compounds in the preparation of a new class of lanthanides and other coordination compounds. Our initial studies on the application of these catalysts have been made in the epoxide opening reaction.

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DOI: 10.5151/chempro-14bmos-R0368-1

Referências bibliográficas

• [1] 1 Evans, D. A.; Miller, S. J.; Lectka, T. J. Am. Chem. Soc. 1993, 115, 6460.
• [2] 2 (a) Molander, G. A.; Hahn, G. J. Org. Chem. 1986, 51, 2596; (b) Schaus, S. E.; Jacobsen, E. N. Org. Lett. 2000, 2, 1001.

Como citar:

Toledo, P. R. S.; Oliveira, D. M.; Ferreira, J. G.; Leotério, D. M. S.; Alves Jr, S.; Princival, J. L.; "Synthesis of novel optically active ligants to coordination chemistry and its application in the organic reactions", p-368-368. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0368-1