Study of photo-degradation of new 2-oxazoline telluride derivative.

Study of photo-degradation of new 2-oxazoline telluride derivative.

Oliveira, Alfredo R. Marques; Mello, Murilo B.Marcondes de

Abstract:

The photooxidation products of di-benzyl-tellurides and arylalkyl tellurides were described by Cava and Clive. Ferreira3 studied the photodegradation process for arylbenzyltellurides. All this results indicates that the processes must be mediated by one or more radicalar steps. On the other hand radical tellurides derivatives have considerable potential for use in organic synthesis. In this work, is shown the first results of the synthesis of a 2-oxazoline telluride derivative and its photo-degradation behavior.

The photooxidation products of di-benzyl-tellurides and arylalkyl tellurides were described by Cava and Clive. Ferreira3 studied the photodegradation process for arylbenzyltellurides. All this results indicates that the processes must be mediated by one or more radicalar steps. On the other hand radical tellurides derivatives have considerable potential for use in organic synthesis. In this work, is shown the first results of the synthesis of a 2-oxazoline telluride derivative and its photo-degradation behavior.

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DOI: 10.5151/chempro-14bmos-R0335-1

Referências bibliográficas

• [1] CAPES, CNPQ, UFPR and F.Araucária for the financial suport. The authors also thanks to Prof. Dr. J.V. Comasseto, Alcindo dos Santos and the IQUSP for the HRMS analysis. EFERENCES
• [2] LEE, H., CAVA, M. P., Journal of the Chemical Society, Chemical Communications, 1981, 277-278.
• [3] CRICH, D., CHEN, C., HWANG, J. T., YUAN, H. W., PAPADATOS, A., WALTER, R. I., Journal of the American Chemical Society, 1994, 116, p.8937-8951. J.T.B., Oliveira, A.R.M.,. Comasseto, J.V., Tetrahedron Lett., 1992,33, 915
• [4] OBA, M., ENDO, M., NISHIYAMA, K., OUCHI, A., ANDO, W., Chemical Communications 2004, 1672-1673,.
• [5] OUCHI, A., HYUGANO, T., LIU, C., Organic Letters, 2009, 11, 4870-4873.
• [6] MEYERS, A. I. The Journal of Organic Chemistry, 2005, 70, 6137-6151.

Como citar:

Oliveira, Alfredo R. Marques; Mello, Murilo B.Marcondes de; "Study of photo-degradation of new 2-oxazoline telluride derivative.", p-335-335. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0335-1