Structural assignment of the trimethylsilyl-protected cyanohydrins of R-(-)-carvone.

Structural assignment of the trimethylsilyl-protected cyanohydrins of R-(-)-carvone.

Alves, Leandro de C.; Desiderá, André L.; Oliveira, Kleber T. de; Ferreira, Antonio G.; Brocksom, Timothy J.

Abstract:

In the course of our studies on the synthesis of perhydroazulene terpenes, we have already determined the structures 2 and 2a, and the (dr), of the cyclopropanation of R-(-)-carvone (1) (Scheme 1, A). We now present a similar study of the 1,2 addition of cyanide (Scheme 1, B).

In the course of our studies on the synthesis of perhydroazulene terpenes, we have already determined the structures 2 and 2a, and the (dr), of the cyclopropanation of R-(-)-carvone (1) (Scheme 1, A). We now present a similar study of the 1,2 addition of cyanide (Scheme 1, B).

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DOI: 10.5151/chempro-14bmos-R0192-1

Referências bibliográficas

• [1] 1 Brocksom, T. J., Brocksom, U., Sousa, D. P, Frederico, D. Tetrahedron Asym., 2005, 16, 362.
• [2] 2 Faria, M. L; Magalhães, R. A.; Silva, F. C.; Matias, L. G. O.; Ceschi, M. A.; Brocksom, U; Brocksom, T. J. Tetrahedron Asym., 2000,11, 4093.
• [3] 3 Corey, E. J.; Chaykovsky, M. J. Am. Chem. Soc. 1965, 87, 1353.

Como citar:

Alves, Leandro de C.; Desiderá, André L.; Oliveira, Kleber T. de; Ferreira, Antonio G.; Brocksom, Timothy J.; "Structural assignment of the trimethylsilyl-protected cyanohydrins of R-(-)-carvone.", p-192-192. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0192-1