Selective oxidations of organoboron compounds catalyzed by Baeyer-Villiger monooxygenases

Selective oxidations of organoboron compounds catalyzed by Baeyer-Villiger monooxygenases

Brondani, Patrícia B.; Gonzalo, Gonzalo de; Fraaije, Marco W.; Andrade, Leandro H.

Abstract:

BVMOs are known for performing the oxidation of aldehydes and ketones to their corresponding esters, the oxygenation of heteroatoms (sulfur, nitrogen, phosphorus, boron, selenium) and even epoxidation reactions. In this work we have explored BVMOs and organoboron compounds as well as racemic ones as target substrates in BVMOs-catalyzed oxidation reaction.

BVMOs are known for performing the oxidation of aldehydes and ketones to their corresponding esters, the oxygenation of heteroatoms (sulfur, nitrogen, phosphorus, boron, selenium) and even epoxidation reactions. In this work we have explored BVMOs and organoboron compounds as well as racemic ones as target substrates in BVMOs-catalyzed oxidation reaction.

Palavras-chave:

DOI: 10.5151/chempro-14bmos-R0097-2

Referências bibliográficas

• [1] 1 a)Torres Pazmiño, D. E.; Dudek, H.; Fraaije, M. W.; Curr. Opin. Chem. Biol. 2010, 14, 138. b) Nolan, L. C.; O’Connor, K. E. Biotechnol. Lett. 2008, 30, 1879. c) Van Berkel, W. J. H.; Kamerbeek, N. M.; Fraaije, M. W. J.
• [2] Biotechnol. 2006, 124, 670. 2 a) Colonna, S.; Gaggero,N.; Carrea, G. Ottolina, P.; Pasta,P.; Zambianchi, F. Tetrahedron: Lett. 2002, 43, 1797. b) Branchaud, B. P.; Walsh, C. T. J. Am. Chem. Soc. 1985, 107, 2153. 3 Patti, A.; Pedotti, S.; Sanfilippo,C. Chirality 2007, 19, 344.

Como citar:

Brondani, Patrícia B.; Gonzalo, Gonzalo de; Fraaije, Marco W.; Andrade, Leandro H.; "Selective oxidations of organoboron compounds catalyzed by Baeyer-Villiger monooxygenases", p-97-97. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0097-2