Março 2021 vol. 8 num. 1 - XXVIII SIMPÓSIO INTERNACIONAL DE ENGENHARIA AUTOMOTIVA

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Influência da degradação de catalisadores de três vias nas emissões de NH3 e N2O em motociclos.

Influence of the degradation of three-way catalysts on NH3 and N2O emissions in motorcycles.

Daemme, Luiz Carlos ; Neto, Renato de Arruda Penteado ; Chedid, Juliano Pazello ; Zotin, Fatima Maria Zanon ; Errera, Marcelo Risso ;

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Com o crescimento da frota de motociclos e devido à relevância de suas emissões de gases poluentes, foi implantado o PROMOT em 2002. O programa estipulou um cronograma para redução gradual das emissões, sendo necessária a adoção de novas tecnologias e sis

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With the growth of the motorcycle fleet and due to the relevance of its pollutant gas emissions, PROMOT was implemented in Brazil in 2002. The program implemented a schedule for the gradual reduction of emissions, requiring the implementation of new techn

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DOI: 10.5151/simea2021-PAP56

Referências bibliográficas
  • [1] DAEMME, L. C. Estudo da emissão de aldeídos em motociclos. 2012. 124 f. Dissertação (Mestrado em Desenvolvimento de Tecnologia) - Programa de Pós-Graduação em Desenvolvimento de Tecnologia – PRODETEC, Instituto de Tecnologia para o Desenvolvimento - LACTEC, Curitiba, 2012.
  • [2] DAEMME, L. C. Modelo para determinação de fatores de emissão em veículos leves de passageiros e motociclos. Tese (Doutorado) — PPG, UFPR, Curitiba, Brasil, 2017.
  • [3] MENDES, E. M. Avaliação de programas de controle de poluição atmosférica por veículos leves no Brasil. 189f. Tese (Doutorado em Ciências em Planejamento Energético) – Setor de Ciências, Universidade Federal do Rio de Janeiro, Rio de Janeiro, 2004.
  • [4] SHELEF, M.; MCCABE, R. W. Twenty-five years after introduction of automotive catalysts: what next. Catalysis today, v. 62, n. 1, p. 35-50, 2000. ISSN 0920-5861.
  • [5] HECK, R. M.; FARRAUTO, R. J. Automobile exhaust catalysts. Applied Catalysis A: General, v. 221, n. 1, p. 443-457, Nov. 2001. ISSN 0926-860X.
  • [6] RANGEL, M. do C.; CARVALHO, M. F. A. Impacto dos catalisadores automotivos no controle da qualidade do ar. Química Nova, v. 26, n. 2, p. 265-277, 2003. ISSN 0100-4042.
  • [7] MATSUMOTO, S. I. Recent advances in automobile exhaust catalysts. Catalysis Today, v. 90, n. 3, p. 183-190, July 2004. ISSN 0920-5861.
  • [8] ZHAO, F. F. Technologies for near-zero-emission gasoline-powered vehicles. SAE International, 2007.
  • [9] HARVEY, C. A.. GARBE, R.; BAINES, T.; SOMERS, J.; HELLMAN, K.; CAREY, P. A study of the potential impact of some unregulated motor vehicle emissions. SAE Technical Paper 830987, 1983.
  • [10] ODAKA, M.; KOIKE, N.; SUZUKI, H. Influence of catalyst deactivation on N2O emissions from automobiles. Chemosphere - Global Change Science, v. 2, n. 3-4, p. 413-423, July 2000. ISSN 1465-9972.
  • [11] DURBIN, T. D.; WILSON, R.; NORBECK, J.; MILLER, W.; HUAI, T; RHEE, S. Estimates of the emission rates of ammonia from light-duty vehicles usingstandard chassis dynamometer test cycles. Atmospheric Environment, v. 36, n. 9, p. 1475-1482, Mar. 2002. ISSN 1352-2310.
  • [12] HEEB, N. V.; FORSS, A.M.; BRUHLMANN, S.; LUSCHER, R.; SAXER, C.; HUG, P. Three-way catalyst-induced formation of ammonia—velocity-and acceleration-dependent emission factors. Atmospheric Environment, v. 40, n. 31, p. 5986-5997, Oct. 2006. ISSN 1352-2310.
  • [13] LIVINGSTON, C.; RIEGER, P.; WINER, A. Ammonia emissions from a representative in-use fleet of light and medium-duty vehicles in the California South Coast Air Basin. Atmospheric Environment, v. 43, n. 21, p. 3326-3333, July 2009. ISSN 1352-2310.
  • [14] PENTEADO, R.; DAEMME, L.C.; ZOTIN, F.M.Z.; KRAHL, J. A study on regulated and unregulated emissions from a set of five gasoline and ethanol fueled motorcycles. In: FISITA 2012 WORLD AUTOMOTIVE CONGRESS, 34., Beijing, 2013. Heidelberg: Springer, 2013. v. 189, cap. 53, p. 687-698. (Lecture Notes in Electrical Engineering). ISBN 978-3-642-33840-3.
  • [15] DAEMME, L. C.; PENTEADO, R.; ZOTIN, F.M.Z.; ERERRA, M. Regulated and unregulated emissions from a Flex Fuel motorcycle fuelled with various gasoline/ethanol blends. SAE Technical Paper 2014-32-0032, 2014d.
  • [16] SUN, K.; TAO, L.; MILLER, D.; PAN, D.; GOLSTON, L.; ZONDLO, M.; GRIFFIN, R.; WALLACE, H.W.; LEONG, Y.; YAN, M.; ZHANG, Y.; MAUZERALL, D.; ZHU, T. Vehicle Emissions as an important urban ammonia source in the United States and China. Environmental Science & Technology, v. 51, n. 4, p. 2472-2481, 2017. ISSN 0013-936X.
  • [17] ANDRADE, M. ; MIRANDA, R. ; FORNARO, A. ; KERR, A.; OYAMA, B.; ANDRE, P.; SALDIVA, P. Vehicle emissions and PM2. 5 mass concentrations in six Brazilian cities. Air Quality, Atmosphere & Health, v. 5, n. 1, p. 79-88, 2012. ISSN 1873-9318.
  • [18] WHO - World Health Organization. IARC: outdoor air pollution a leading environmental cause of cancer deaths. Press Release, n. 221, 13 Oct. 2013.
  • [19] BATTYE, W.; ANEJA, V. P.; ROELLE, P. A. Evaluation and improvement of ammonia emissions inventories. Atmospheric Environment, v. 37, n. 27, p. 3873-3883, Apr. 2003. ISSN 1352-2310.
  • [20] DAEMME, L. C. ; PENTEADO, R. ; ERRERA, R.M.; ZOTIN, F.M.Z. Estudo preliminar sobre a influência do teor de enxofre do combustível na emissão de amônia em motociclos e veículos leves dos ciclos Otto e Diesel. In: SIMPÓSIO INTERNACIONAL DE ENGENHARIA AUTOMOTIVA – SIMEA 2013, 21., 2014, São Paulo. São Paulo: Blucher, 2014a. p. 627-636.
  • [21] DAEMME, L. C. PENTEADO, R. ZOTIN, F.M.Z.; RISSO, M. Redução da emissão de amônia em motociclos com uso de um catalisador SCR. In: PRÊMIO AEA DE MEIO AMBIENTE, 8., 2014b. Trabalhos Vencedores – Categoria Acadêmica. Disponível em: .
  • [22] BORSARI, V. Emissão de amônia de veículo automotor leve e sua importância para a Saúde Ambiental. 2015. 180 f. Tese (Doutorado em Saúde Ambiental) - Faculdade de Saúde Pública, Universidade de São Paulo, São Paulo, 2015.
  • [23] DAEMME, L. C. ; PENTEADO, R. ; FURLAN, C.; ERRERA, M.; ZOTIN, F. An investigation on aldehyde and ammonia emissions from a 4-stroke gasoline-fueled motorcycle. ammonia emission reduction by using a SCR catalyst. SAE Technical Paper 2013-36-0181, 2013.
  • [24] BECKER, K.; KURTENBACH, R.; WIESEN, P.; JESEN, T.E.; WALLINGTON, T.J. Nitrous oxide (N2O) emissions from vehicles. Environmental Science & Technology, v. 33, n. 22, p. 4134-4139, Oct. 1999. ISSN 0013-936X.
  • [25] MACHIDA, T.; NAKAZAWA, T.; FUJII, Y.; AOKI, S.; WATANABE, O. Increase in the atmospheric nitrous oxide concentration during the last 250 years. Geophysical Research Letters, v. 22, n. 21, p. 2921-2924, Nov. 1995.
  • [26] WMO. Greenhouse gas concentrations in atmosfer yet another high. World Meteorological Organization, 2019.
  • [27] WMO. Greenhouse Gas Bulletin. N°14, Based on glogal observation, 2018.
  • [28] JIMÉNEZ-PALACIOS, J. L. Understanding and quantifying motor vehicle emissions with vehicle specific power and TILDAS remote sensing. 361 p. Thesis (Mechanical Engineering - Ph.D./Sc.D.) - Massachusetts Institute of Technology - MIT, Cambridge, 1999.
  • [29] HEEB, N. V. ; SAXER, C. ; FORSS, A.M. ; BRUHLMANN, S. Trends of NO-, NO2-, and NH3- emissions from gasoline-fueled Euro-3- to Euro-4-passenger cars. Atmospheric Environment, v. 42, n. 10, p. 2543-2554, Mar. 2008. ISSN 1352-2310.
  • [30] HUAI, T.; DURBIN, D.T. ; MILLER, J. ; NORBECK, J. Estimates of the emission rates of nitrous oxide from light-duty vehicles using different chassis dynamometer test cycles. Atmospheric Environment, v. 38, n. 38, p. 6621-6629, Dec. 2004. ISSN 1352-2310.
  • [31] LIPMAN, T. E.; DELUCCHI, M. A. Emissions of nitrous oxide and methane from conventional and alternative fuel motor vehicles. Climatic Change, v. 53, n. 4, p. 477-516, June 2002. ISSN 1573-1480.
  • [32] SILVA, R. A.; VIANA, M. M.; MOHALLEM, N. D. S. Caracterização textural, morfológica e estrutural de catalisadores automotivos novos e usados. Cerâmica, v. 55, n. 334, p. 170-176, June 2009.
  • [33] BECK, D. D.; SOMMERS, J. W.; DIMAGGIO, C. L. Impact of sulfur on model palladium-only catalysts under simulated three-way operation. Applied Catalysis B: Environmental, v. 3, n. 2-3, p. 205-227, Feb. 1994. ISSN 0926-3373.
  • [34] ZOTIN, F.M.Z.; GOMES, O.F.M.; OLIVEIRA, D.H.; ALCOVER, A.; CARDOSO, M.J.B. Catalysis Today, 107–108 (2005) 157-167.[35] FERNANDES, D.M.; SCOFIELD, C.F.; ALCOVER NETO, A.; CARDOSO, M.J.B.; ZOTIN, F.M.Z chemical engineering journal, 160 (2010) 85-92. [36] ANP. Resolução N°21 Especificações da gasolina de referência para ensaios de avaliação de consumo de combustível e emissões veiculares para homologação de veículos automotores, ciclo Otto, destinadas exclusivamente ao cumprimento da fase L-6 do PROCONVE. Regulamento técnico, 2009.
  • [35] [37] BRASIL. Resolução CONAMA nº 297, de 26 de fevereiro de 2002. Estabelece os limites para emissões de gases poluentes por ciclomotores, motociclos e veículos similares novos. Diário Oficial da União nº 51, Brasília, DF, 15 mar. 2002. Seção 1, p. 86-88.
  • [36] [38] EC - European Union. European Parliament, Council of the European Union. Directive 97/24/EC of the European Parliament and of the Council of 17 June 1997 on certain components and characteristics of two or three-wheel motor vehicles. Official Journal of the European Communities, L 226, v. 40, 18 Aug. 1997. [39] GEIVANIDIS, S.; NTZIACHRISTOS, L.; SAMARAS, Z.; XANTHOPOULOS, A.; STEVEN, H.; BUGSEL, B. Study on possible new measures concerning motorcycle emissions. Report No: 08.RE.0019.V2, Aristotle University Thessaloniki, Nov. 2008.
  • [37] [40] ABNT - Associação Brasileira de Normas Técnicas. NBR 7024: Veículos rodoviários automotores leves — Medição do consumo de combustível - Método de ensaio. Rio de Janeiro, 2010a.
  • [38] [41] CFR - Code of Federal Regulations. Title 40, Part 1065: Engine-testing procedures. Washington DC: US Government Printing Office, 2012.
  • [39] [42] EC - European Union. European Commission. Commission Regulation (EU) no. 64/2012 of 23 January 2012 amending regulation (EU) no. 582/2011 implementing and amending regulation (EC) no. 595/2009 of the european parliament and of the council with respect to emissions from heavy duty vehicles (Euro VI) text with eea relevance. Official Journal of the European Union, L 28, v. 55, 31 Jan. 2012.
  • [40] [43] CARB - California Air Resources Board. SOP No. MLD 147: Procedure for the determination of ammonia in automotive exhaust by Fourier Transform Infrared Spectroscopy. Califórnia: CARB, 2007.
  • [41] [44] BIELACZYC, P.; SZCZOTKA, A.; SWIATEK, A.; WOODBURN, J.. A comparison of ammonia emission factors from light-duty vehicles operating on gasoline, liquefied petroleum gas (LPG) and compressed natural gas (CNG). SAE International Journal of Fuels and Lubricants, v. 5, p. 751-759, 2012. ISSN 1946-3960.
  • [42] [45] LIVINGSTON, C. G. Development and application of a validated method for measurements of ammonia emissions from in-use vehicles on a chassis dynamometer. 2008. 172 p. Thesys (Doctoral) - University of California, ProQuest, Los Angeles, 2008. [46] AIR PRODUCTS. Physical properties for nitrous oxide. 2020.
  • [43] [47] NIST. Ammonia. National Institute of Standards and Technology, 2018.
  • [44] [48] P.G. Boulter, Environmental traffic management: a review of factors affecting cold start emissions Transport Research Laboratory Report, Vol. 270, Prepared for Driver Information and Traffic Management Division, Department of the Environment, Transport and the Regions, Great Britain, 1997. [49] WEILENMANN, M.; SOLTIC, P.; SAXER, C.; FORSS, A.; HEEB, N. Atmospheric Environment 39 (2005) 2433–2441.
  • [45] [50] KEAN, A. J. ; LITTLEJOHN, D. ; HARLEY, R.; BAN-WEISS, G.A.; LAUDEN, M.; KIRCHSTETTER, T. Trends in on-road vehicle emissions of ammonia. Atmospheric Environment, v. 43, n. 8, p. 1565-1570, Mar. 2009. ISSN 1352-2310.
  • [46] [51] BARBIER JR., J.; DUPREZ, D. Steam effects in three-way catalysis. Applied Catalysis B: Environmental, v. 4, n. 2-3, p. 105-140, Sept. 1994. ISSN 0926-3373.
  • [47] [52] WHITTINGTON, B. I.; JIANG, C. J.; TRIMM, D. L. Vehicle exhaust catalysis: I. The relative importance of catalytic oxidation, steam reforming and water-gas shift reactions. Catalysis Today, v. 26, n. 1, p. 41-45, Aug. 1995. ISSN 0920-5861.
  • [48] [53] MEJÍA-CENTENO, I.; CASTILLO, S.; FUENTES, G. A. Enhanced emissions of NH3, N2O and H2 from a Pd-only TWC and supported Pd model catalysts: light-off and sulfur level studies. Applied Catalysis B: Environmental, v. 119–120, p. 234-240, May 2012. ISSN 0926-3373.
  • [49] [54] DURBIN, T. D.; HUAI, T.; NORBECK, J.M.; RHEE, S.H. Investigation of emission rates of ammonia, nitrous oxide and other exhaust compounds from alternative fuel vehicles using a chassis dynamometer. Internacional Journal of Automotive Technology, v. 4, n. 1, p. 9-19, 2003.
  • [50] [55] CHAN, C.; NIEN, C.; TSAI, C.; HER, G. Comparison of Tail-Pipe Emissions from Motorcycles and Passenger Cars. Journal of the Air & Waste Management Association, 45:2, 116-124, DOI: 10.1080/10473289.1995.10467347
  • [51] [56] BARBIER, J. ; DUPREZ, D. Applied Catalysis B: Environmental 4. 1994, 105-140.
  • [52] [57] ZHAO, M.; SHEN, M.; WANG, J.; WANG, W. Influence of Pd Morphology and Support Surface Area on Redox Ability of Pd/Ce0.67Zr0.33O2 under CO-He Pulse and Transient CO-O2 Measurements. Ind. Eng. Chem. Res. 46 (2007) 7883-7890.
  • [53] [58] MEJÍA-CENTENO, I. ; FUENTES , G. Effect of low-sulfur fuels upon NH3 and N2O emission during operation of commercial three-way catalytic converters. Topics in Catalysis, v. 42-43, n. 1-4, p. 381-385, May 2007. ISSN 1022-5528.
  • [54] [59] DAEMME, L. C.; PENTEADO, R.; ZOTIN, F.; CORREA, S.; ERRERA, M.; FORCETTO, A.; VICENTINI, P. Impacto da redução do teor de enxofre da gasolina S800 para S50 nas emissões da frota brasileira, p. 914-929 .In: XXVII Simpósio Internacional de Engenharia Automotiva. São Paulo: Blucher, 2019. ISSN 2357-7592, DOI 10.5151/simea2019-PAP94.15
  • [55] [60] OH, S. H.; TRIPLETT, T. Reaction pathways and mechanism for ammonia formation and removal over palladium-based three-way catalysts: multiple roles of CO. Catalysis Today, v. 231, p. 22-32, Aug. 2014. ISSN 0920-5861.
  • [56] [61] DAEMME, L. C.; PENTEADO, R.; ZOTIN, F.; CORREA, S.; ERRERA, M.; FORCETTO, A. The effect of fuel sulfur content on ammonia, aldehyde and regulated emissions emitted from a Euro III motorcycle. SAE Technical Paper 2016-36-0158, 2016d.
  • [57] [62] DASCH, J. M. Nitrous oxide emissions from vehicles. Journal of the Air & Waste Management Association, v. 42, n. 1, p. 63-67, 1992. ISSN 1047-3289.
  • [58] [63] WALLINGTON, T. J.; WIESEN, P. N2O emissions from global transportation. Atmospheric Environment, v. 94, p. 258-263, Sept. 2014. ISSN 1352-2310.
  • [59] [64] WEISS, R. F.; CRAIG, H. Production of atmospheric nitrous oxide by combustion. Geophysical Research Letters, v. 3, n. 12, p. 751-753, Dec. 1976. ISSN 1944-8007. [65] HAO, W. M.; WOFSY, S.C.; MCELROY, M.B.; BEER, J.M.; TOGAN, M.A. Sources of Atmospheric nitrous oxide from combustion. Journal of Geophysical Research: Atmospheres, v. 92, n. D3, p. 3098-3104, Mar. 1987. ISSN 2156-2202.
  • [60] [66] WANG, Y.; ZHU, A.; ZHANG, Y.; AU, C. T.; YANG, X.; SHI, C. Catalytic reduction of NO by CO over NiO/CeO2 catalyst in stoichiometric NO/CO and NO/CO/O2 reaction. Applied Catalysis B: Environmental 81 (2008) 141–149.
  • [61] [67] FORNASIERO, P.; RAO, G. R.; KASPAR, J.; ERARIO, F.L.; GRAZIANI, M. Reduction of NO by CO over Rh/CeO2–ZrO2 catalysts. J. Catal. v. 175, p. 269–279, 1998.
  • [62] [68] GRANGER, P.; LECLERCQ, G. Reduction of N2O by CO over Ceria-Modified Three-Way Pt−Rh Catalysts: Kinetic Aspects. J. Phys. Chem. C, v. 111, n. 27, p. 9905-9913, 2007.
Como citar:

Daemme, Luiz Carlos; Neto, Renato de Arruda Penteado; Chedid, Juliano Pazello; Zotin, Fatima Maria Zanon; Errera, Marcelo Risso; "Influência da degradação de catalisadores de três vias nas emissões de NH3 e N2O em motociclos.", p. 235-250 . In: Anais do XXVIII SIMPÓSIO INTERNACIONAL DE ENGENHARIA AUTOMOTIVA. São Paulo: Blucher, 2021.
ISSN 2357-7592, DOI 10.5151/simea2021-PAP56

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