Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

Abstract - Open Access.

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Electrochemical homo-coupling of benzyl halides on a powder cathode in a cavity cell

Silva, Renato A. da ; Souza, Ronny F. M. de ; Areias, Madalena C. C. ; Navarro, Marcelo ; Bieber, Lothar W. ;

Abstract:

The main challenge in organic synthesis is the formation of new C-C bonds in order to construct more complex carbon skeletons in a defined arrangement. In contemporary electrochemical publications, such C-C couplings are still a minor subject. Herein we reported an application of a new electrochemical cell which uses graphite powder in the cathode cavity combined with an aqueous anolyte to promote the dimerization of benzyl halides in good yield.

Abstract:

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Palavras-chave: cavity cell, benzyl halides, solvent-free,

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DOI: 10.5151/chempro-14bmos-R0203-2

Referências bibliográficas
  • [1] 1 Yoshida, J.; Katoaka, K.; Horcajada, R.; Nagaki, A. Chem. Rev. 2008, 108, 2265.
  • [2] 2 Areias, M. C. C.; Navarro, M.; Bieber, L. W.; Diniz, F. B.; Leonel, E.; Cachet-Vivier, C.; Nedelec, J. Y. Electrochim. Acta, 2008, 53, 6477.
  • [3] 3 Souza, R. F. M.; Souza, C. A.; Areias, M. C. C.; Cachet-Vivier, C.; Laurent, M.; Barhdadi, R.; Navarro, M.; Bieber, L. W. Electrochim. Acta, 2010, 56, 575.
  • [4] 4 Souza, R. F. M.; Areias, M. C. C.; Bieber, L. W.; Navarro, M. Green Chemistry, 2011, DOI: 10.1039/C0GC00947D, Communication.
Como citar:

Silva, Renato A. da; Souza, Ronny F. M. de; Areias, Madalena C. C.; Navarro, Marcelo; Bieber, Lothar W.; "Electrochemical homo-coupling of benzyl halides on a powder cathode in a cavity cell", p. 203 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0203-2

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