Charge-tagged ligands derived of 1,3-imidazolium ion as catalyst precursor of copper, nickel and palladium

Charge-tagged ligands derived of 1,3-imidazolium ion as catalyst precursor of copper, nickel and palladium

Oliveira, Felipe F. D.; Lalli, Priscila M.; Schmidt, Eduardo M.; Bakuzis, Peter; Lapis, Alexandre A. M.; Eberlin, Marcos N.; Neto, Brenno A. D.

Abstract:

ESI-MS is a soft ionizing technique, which may allow an online monitoring of a plethora of reactions. Valuable information such as coordination, oxidation states of metal center and others may be obtained by ESI-MS. Based on that, we synthesized a charge-tagged ligand as a precursor to an in situ formation of a charge-tagged catalyst palladium, cooper and nickel. Herein, we describe the gas phase chemistry of the palladium-derivatives.

ESI-MS is a soft ionizing technique, which may allow an online monitoring of a plethora of reactions. Valuable information such as coordination, oxidation states of metal center and others may be obtained by ESI-MS. Based on that, we synthesized a charge-tagged ligand as a precursor to an in situ formation of a charge-tagged catalyst palladium, cooper and nickel. Herein, we describe the gas phase chemistry of the palladium-derivatives.

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DOI: 10.5151/chempro-14bmos-R0144-1

Referências bibliográficas

• [1] 1 R. G. Cooks, H. Chen, M. N. Eberlin, X. Zheng, W. A. Tao, Chem. Rev. 2006, 106, 188-211.

Como citar:

Oliveira, Felipe F. D.; Lalli, Priscila M.; Schmidt, Eduardo M.; Bakuzis, Peter; Lapis, Alexandre A. M.; Eberlin, Marcos N.; Neto, Brenno A. D.; "Charge-tagged ligands derived of 1,3-imidazolium ion as catalyst precursor of copper, nickel and palladium", p-144-144. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-14bmos-R0144-1