Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

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Cross-Coupling Reaction of Organotellurolates with Aryl Iodides Catalyzed by CuI

Silva, Márcio S. ; Comasseto, João V. ;

Abstract:

Transition metal catalyzed cross-coupling reactions of organic electrophiles and organometallic reagents allows the formation of new carbon-carbon and carbon-heteroatom bonds. Several catalytic systems have been developed for the formation of C-N, C-O, and C-S bonds. However, very few reports on the formation of C-Te bonds by this process are available. In this work, we report the synthesis of aryl alkyl tellurides by the reaction of aryl iodides with lithium alkyltellurolates promoted by CuI.

Abstract:

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Palavras-chave: Organotellurolates, Aryl Iodides, Copper Iodide,

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DOI: 10.5151/chempro-14bmos-R0136-2

Referências bibliográficas
  • [1] 1 Hartwig, J. F. In Handbook of Organopalladium Chemistry for Organic Synthesis; Negishi, E. Ed. Wiley-Interscience: New York, 2002.
  • [2] 2 Beletskaya, I. P.; Ananikov, V. P. Chem. Rev. 2011, 111, 1596-1636.
Como citar:

Silva, Márcio S.; Comasseto, João V.; "Cross-Coupling Reaction of Organotellurolates with Aryl Iodides Catalyzed by CuI", p. 136 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0136-2

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